When you eat or drink something that tastes good at first but then tastes like ass right after.
Ex 1.
Moiz: "This juice is good at first but then shitty afterwards .
Zach: "Dude, you've got a serious case of after-ass."
Ex 2.
"I ate this chick's ass and at the time it tasted good, but then I started tasting that after-ass when I was done"