To have sex with someone, sometimes in a controlling manner.
Becky: "I got skippered by the Tuna Captain last night.
Michelle: "Becky you dirty slut! You know he's skippered half the town already right!?"
Becky: "I know! But he just has a way of talking a girl into it!"
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A man who skippers lots of Tuna - or has sex with a lot of women.
Sam: "Hey Mike, is that the Tuna Captain talking to your girlfriend?"
Mike: "Oh shit. It is. You don't think he's skippered her, do you???"
Sam: "Probably. Guess you're single again."
Mike: "Fuck the Tuna Captain."
Sam: "Yeah, she already did, dude."