Designated for assignment, a step that a Major League Baseball team takes in order to send a (soon-to-be former) major league player back to the minors under certain contractual conditions. "DFA" is often used as a verb.
"That player hit his ceiling, so the general manager DFA'ed him."
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To transfer saliva from the mouth to some surface by flicking (throwing, tossing) it from the mouth onto that surface using the thumb and index fingers, and a flicking motion from the wrist (like throwing a dart).
During intercourse, Jeremy splicked; rather than spit; on his target (which needed to be more wet), so he wouldn't miss.