An employee who works at a Pick 'n' Save grocery store, most likely against their will.
Billy was a Pick-n-slave, until he found a job that paid twice as much. He then bid the rest of his co-slaves farewell and went on to bigger and better things.
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To "get the gunk out" or to clean the mess out or off of something.
After eating the whole bag of gum drops, Jake found it hard to degunkify his teeth.