A D&D (or other similar system) character who uses their chaotic alignment (usually chaotic neutral) as an excuse to do whatever they want, even if it's obviously a lethally bad idea, will piss off the other players, is extremely out-of-character, or a combination of the three.
DM: You see a large corridor with a desk at the end.
Player 1: Whose desk is it?
DM: The nametag on the door behind you said "Planetar General".
Player 2: I shit on the desk.
Player 1: Dude no don't you'll get us killed.
DM: Are you sure you want to do that?
Player 2: My character is chaotic neutral, and as such would do this very stupid thing for the sole reason of causing chaos, regardless of consequences or how anyone else would react.
Player 1: More like Chaotic Stupid.
The act of being completely organised in some aspects of life, and completely unorganised in other aspects, such that your organisation itself is unorganised.
John had all his correct books organised for his day at school, but had no idea what lessons he had when, finding out from his friends as the day went on. John is chaotically unorganised.
An alignment out of the 9 Dungeons and Dragons alignments that focuses his or her's life on doing what they believe is right and wrong. They'll bring peace safety, tranquility, and most importantly freedom across society.
Mario: So Mark what's your D and d alignment,
daniel: Chaotic neutral
Selena: Lawful; good
Mark: Chaotic good, sick of this stupid system knowing so much about treating people differently instead of the same with kindeess and respect.
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having a strict moral code, but it is so confusing no one can figure out what it is
Person: if your parents had an alignment, what would it be
another person: definitely chaotic lawful.
Someone who has no readable energy and never stops shitposting. Goes for high-effort shitposts and is probably a top.
Freind 1: How was your grindr date?
Friend 2: It was cool, found out he's a chaotic shitposter
When someone of the opposite sex makes your pants go crazy.
Dude, when Allison touches me, it causes chaos in my underloins! You know, like the movie, Chaotic underloins.