When someone goes Puerto Rico on someone or when someone goes to Puerto Rico during sex, it means that she/he/div. licked the other person's genitals-more specifically the other's person asshole, because the person goes singing "ay ay ay (Puerto Rico)" from the excitement.
-So, how did it go last night?
-She/he/div. went Puerto Rico on me.
Or
She/he/div. went to Puerto Rico on me and I was like "ay ay ay".
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A warm Caribbean island. It's owned by the United States (as a territory) but has plenty of Spanish influence. I practiced my Spanish there and to my surprise, up in the mountains of the interior, they didn't speak much English. They run on "Latin Time" too.
Many tourists coming to Puerto Rico just stay in San Juan-they don't explore the west, east, central, and southern parts of the island-something I recommend doing.