in reference to a D&D character, extremely dumb and unintelligent. One can be classified as chaotic stupid if they do such things as taking a more complicated way to do things, or do something the party has told them not to, for no reason.
DM: "Okay guys, you enter into the room and there's a button in the middle of the room."
Player 1: "Okay. Don't press the button guys. It could be a trap. Let's just continue."
Player 2: "What colour is this button?"
Player 1: "Does that matter?"
DM: "It's bright red like the buzzers on Family Feud."
Player 2: "I can't resist it. I push the button."
Player 1: "Really? We got Mr. Chaotic Stupid over here don't we?"
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A character in Dungeons & Dragons games with a "Chaotic Evil" alignment, played poorly and to the detriment of the game, usually resulting in the deaths of the character and his allies.
(See also: Lawful Stupid)
Chaotic Stupid Player: I kill the girl.
DM: ...Why?
Chaotic Stupid Player: Because I'm evil.
DM: Okay, you murder the little girl in front of everyone to show how totally badass and evil you are. The militia charge you down and kill you.
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A D&D (or other similar system) character who uses their chaotic alignment (usually chaotic neutral) as an excuse to do whatever they want, even if it's obviously a lethally bad idea, will piss off the other players, is extremely out-of-character, or a combination of the three.
DM: You see a large corridor with a desk at the end.
Player 1: Whose desk is it?
DM: The nametag on the door behind you said "Planetar General".
Player 2: I shit on the desk.
Player 1: Dude no don't you'll get us killed.
DM: Are you sure you want to do that?
Player 2: My character is chaotic neutral, and as such would do this very stupid thing for the sole reason of causing chaos, regardless of consequences or how anyone else would react.
Player 1: More like Chaotic Stupid.