Someone who is "Painting their face" is lying to themselves. They paint their face as a clown does.
"I swear to god I will wake up early tomorrow to do my homework!!" <- painting their face
"I will start going to the gym this semester" <- painting their face
"Hey, I think I'm going to start applying for jobs!" "You're Painting your face, dawg."
Basically saying im gonna nut in your face...
Hey girl ill paint your face