When you completely ignore someone.
Example 1:
Person 1: Dave?
Person 1: Davveee?!
Person 1: OOh you putting a mental block on me ehh?
This can then be adapted for wherever you are such as a room block.
Example 2:
Person 1: Dave?
Person 2: Alright Dave how are ya?
Person 3: Hes put a room block on us all.
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When you really hate someone and wanna block them but they don’t hate you and you don’t want to seem rude, so you imagine that you blocked them to make yourself feel better.
That guy is now mentally blocked