A poop-shoot face is someone, usually a middle age woman, who always has the look on her face as if something is being shoved up her anus.
Also, a woman who you can tell by looking at her that enjoys anal intercourse.
ex.1 By the look on Nancey's face I could have swore she saw something horrid outside the window, but it turns out she is just a poop-shoot face.
ex.2 Nicki Minaj is such a poop-shoot face. I'd totally give it to her.
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