When someone looks perpetually angry or bitchy or insert other negative adjective here, but it's really just their face. When you meet them later, you realize they are a nice person, but the first impression is that they've got a stick up their ass.
Person 1: Have you seen Josie today? She was mugging me in the hallway.
Person 2: Aw, no, don't take it personally. That's just her face.
James: Did you see Henry today? He looks so stoned.
Timothy: Oh, no that's just his face.
Jim: Do you know who Jenny is?
Bob: Yeah, she seems like such a bitch.
Jim: Oh, well I talked to her today and she actually is really nice. That's just her face.
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The opposite of butter face; when a person has a beautiful face, but a terrible body.
Keira Knightly is such a just her face.