1) An narrow opening and vunerable area in one's armor that the opponent will usually aim for. This term relies on "chink" in the sense of "a crack or gap," a meaning dating from about 1400 and used figuratively since the mid-1600s.
2) A figurative term for a one's weakness, largest flaw or their prevention of success.
1) Because of the chink in the armor of Sir Lancelot, his opponent was able to break past his defense and inflict a dangerous flesh wound.
2) We would have aced this presentation if Leo wasn't in our group. He didn't study at all, he's the chink in the armor.
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