Short for Cop
If you're being called an Op you probably snitched on them or told a secret.
Being called an Op is not a good thing, it means you betrayed their trust and they're probably angry with you.
Person One: Yeah, I accidentally told my mom that you broke her TV...
Person Two: Seriously Op? Now she gonna tell my mom. I'm gonna get my ass whooped.
Person One: I'm so sorry bro