A word usually accompanied by pointing in a specific direction, signifying that something "went that way"
Person A: Where's bill at?
Person B: he said he has herphlees and that it makes him shit every three minutes he shaddled over thataway. (Points towards the shitter)
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Thataway, is a countrified way of telling someone to take a Left Turn. Not to be confused with "Thisaway" which is the countrified way of telling someone to take a Right Turn.
Homer: So when I get to the fork in the road, I go Thataway, instead of Thisaway.